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Publications Klaus Eichele
ORCiD: 0000-0002-9318-5782 see at ORCiD
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F. Kracht, P. Rolser, K. Eichele, C. Maichle-Mössmer, R. Anwander,
Carbon dioxide affinity ("carboxophilicity") of trivalent light metal pyrazolates,
Inorg. Chem. Frontiers 2024, 11, 6948 - 6959.
DOI: 10.1039/D4QI01656D
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K. D. Röseler, K. Eichele, M. Ströbele, H.-J. Meyer,
Crystallization of the Fundamental Tetracyanamidometallates Li4[Si(CN2)4] and Li4[Ge(CN2)4] from Polymeric Li-T-(NCN)-I Precursors (T=Si, Ge),
Eur. J. Inorg. Chem. 2024, 27(14), e202300713.
DOI: 10.1002/ejic.202300713
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M. Auer, K. Zwettler, K. Eichele, H. Schubert, C. P. Sindlinger, L. Wesemann,
Synthesis of Cobalt-Tin and -Lead Tetrylidynes - Reactivity Study of the Triple Bond,
Angew. Chem. Int. Ed. 2023, 62, e202305951.
DOI: 10.1002/anie.202305951
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M. Zweigart, K.Eichele, H. Schubert, C. P. Sindlinger, L. Wesemann,
Authentic Sn=B-Double Bonds in Polar Stannaborene Derivatives,
J. Am. Chem. Soc. 2023, 145, 12452-12458.
DOI: 10.1021/jacs.3c03744
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M. Zweigart, C. Wenzel, K. Eichele, H. Schubert, L. Wesemann,
Stiba-, Arsa- and Phosphastannenes: Syntheses and Reactivities,
Angew. Chem. Int. Ed. 2023, 62, e202304200.
DOI: 10.1002/anie.202304200
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R. H. Kern, M. Schneider, K. Eichele, H. Schubert, H. F. Bettinger, L. Wesemann,
Boradigermaallyl: (4 + 3) Cycloaddition-Initiated Boron Insertion into Benzene,
Angew. Chem. Int. Ed. 2023, 62, e202301593.
DOI: 10.1002/anie.202301593
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M. Auer, J. Bolten, K. Eichele, H. Schubert, C. P. Sindlinger, L. Wesemann,
Heavy Metalla Vinyl-Cations show Metal-Lewis Acid Cooperativity in Reaction with Small Molecules (NH3, N2H4, H2O, H2),
Chem. Sci. 2023, 514-524.
DOI: 10.1039/D2SC05620H
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M. Widemann, F. S. W. Aicher, M. Bonath, K. Eichele, C. Maichle-Mössmer, H. Schubert, P. Sirsch, R. Anwander, L. Wesemann,
Molecular Ln(III)-H-E(II) Linkages (Ln = Y, Lu; E = Ge, Sn, Pb),
Chem. Eur. J. 2022, e20221032.
DOI: 10.1002/chem.202201032
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M. Auer, F. Diab, K. Eichele, H. Schubert, L. Wesemann:
Reactivity of organogermanium and organotin trihydrides
Dalton Trans. 2022, 51, 5950-5961.
DOI: 10.1039/D2DT00681B
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M. Widemann, S. Jeggle, M. Auer, K. Eichele, H. Schubert, C. P. Sindlinger, L. Wesemann:
Hydridotetrylene [Ar*EH] (E = Ge, Sn, Pb) coordination at tantalum, tungsten, and zirconium
Chem. Sci. 2022, 13, 3999-4009.
DOI: 10.1039/D2SC00297C
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M. Löber, M. Ströbele, K. Eichele, C. P. Romao, H.-J. Meyer:
The Lithium Iodostannate LiSn3I7: Synthesis, Properties and its Relationship to SnI2
Eur. J. Inorg. Chem. 2021(47), 4929-4934.
DOI: 10.1002/ejic.202100771
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M. Wiedemair, H. Kopacka, K. Wurst, T. Müller, K. Eichele, S. Vanicek, S. Hohloch, B. Bildstein:
Rhodocenium Functionalization Enabled by Half-Sandwich Capping, Zincke Reaction, Diazoniation and Sandmeyer Chemistry
Eur. J. Inorg. Chem. 2021(32), 3305-3313.
DOI: 10.1002/ejic.202100525
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D. Raiser, K. Eichele, H. Schubert, L. Wesemann:
Phosphine-Stabilized Pnictinidenes
Chem. Eur. J. 2021, 27(56), 14073-14080.
DOI: 10.1002/chem.202102320
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S. Weiß, M. Widemann, K. Eichele, H. Schubert, L. Wesemann:
Low valent lead and tin hydrides in reactions with heteroallenes
Dalton Trans. 2021, 50, 4952-4958.
DOI: 10.1039/D1DT00542A
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J.-J. Maudrich, F. Diab, S. Weiß, M. Zweigart, K. Eichele, H. Schubert, R. Müller, M. Kaupp, L. Wesemann:
Tetryl-Tetrylene Addition to Phenylacetylene
Chem. Eur. J. 2021, 27(14), 4691-4699.
DOI: 10.1002/chem.202005119
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M. Widemann, K. Eichele, H. Schubert, C. P. Sindlinger, S. Klenner, R. Pöttgen, L. Wesemann:
Synthesis and Hydrogenation of Heavy Homologues of Rhodium Carbynes: [(Me3P)2(Ph3P)RhE-Ar*] (E=Sn, Pb)
Angew. Chem. Int. Ed. 2021, 60(11), 5882-5889.
DOI: 10.1002/anie.202015725
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A. Mortis, D. Barisic, K. Eichele, C. Maichle-Mössmer, R. Anwander:
Scandium bis(trimethylsilyl)methyl complexes revisited: extending the(45)Sc NMR chemical shift range and a new structural motif of Li[CH(SiMe3)(2)]
Dalton Trans. 2020, 49(23), 7829-7841.
DOI: 10.1039/d0dt01247e
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N. R. Wiedmaier, H. Speth, G. Leistikow, K. Eichele, H. Schubert, H. A. Mayer, L. Wesemann:
Conformation controlled stepwise hydride shuffling from the metal to the ligand backbone
Dalton Trans. 2020, 49(21), 7218-7227.
DOI: 10.1039/d0dt01431a
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J.-J. Maudrich, F. Diab, S. Weiß, M. Widemann, T. Dema, H. Schubert, K. M. Krebs, K. Eichele, L. Wesemann:
Deprotonation of Organogermanium and Organotin Trihydrides
Inorg. Chem. 2019, 58(23), 15758-15768.
DOI: 10.1021/acs.inorgchem.9b01822
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R. Schmidt, M. Strobele, K. Eichele, H.-J. Meyer:
Lithium Ion Motion in Lithium Nitridoborate Chalcogenides Li-5(BN2)Ch (Ch = Se, Te)
Z. Anorg. Allg. Chem. 2019, 645(4), 461-465.
DOI: 10.1002/zaac.201800432
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C. O. Hollfelder, L. N. Jende, H.-M. Dietrich, K. Eichele, C. Maichle-Mössmer, R. Anwander:
1,3-Diene Polymerization Promoted by Half-Sandwich Rare-Earth-Metal Dimethyl Complexes: Active Species Clustering and Cationization/Deactivation Processes
Chem. Eur. J. 2019, 25(30), 7298-7302.
DOI: 10.1002/chem.201901269
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F. Diab, F. S. W. Aicher, C. P. Sindlinger, K. Eichele, H. Schubert, L. Wesemann:
Reductive Elimination and Oxidative Addition of Hydrogen at Organostannylium and Organogermylium Cations
Chem. Eur. J. 2019, 25(17), 4426-4434.
DOI: 10.1002/chem.201805770
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S. Weiß, M. Auer, K. Eichele, H. Schubert, L. Wesemann:
eta3-Allyl Coordination at Pb(II)
Organometallics 2019, 38(2), 417-423.
DOI: 10.1021/acs.organomet.8b00766
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F. S. W. Aicher, K. Eichele, H. Schubert, L. Wesemann:
Complete Hydrogen Transfer: Tin Hydride Reactivity toward Adamantylisonitrile and Benzonitrile
Organometallics 2018, 37(11), 1773-1780.
DOI: 10.1021/acs.organomet.8b00207
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J. Henoch, A. Auch, F. Diab, K. Eichele, H. Schubert, P. Sirsch, T. Block, R. Pöttgen, L. Wesemann:
Cyclic Distannene or Bis(stannylene) with a Ferrocenyl Backbone: Synthesis, Structure, and Coordination Chemistry
Inorg. Chem. 2018, 57(7), 4135-4145.
DOI: 10.1021/acs.inorgchem.8b00317
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P. Meixner, K. Batke, A. Fischer, D. Schmitz, G. Eickerling, M. Kalter, K. Ruhland, K. Eichele, J. E. Barquera-Lozada, N. P. M. Casati, F. Montisci, P. Macchi, W. Scherer:
J(Si,H) Coupling Constants of Activated Si-H Bonds
J. Phys. Chem. A 2017, 121(38), 7219-7235.
DOI: 10.1021/acs.jpca.7b05830
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R. Schmidt, M. Strobele, K. Eichele, H.-J. Meyer:
Crystal Structure and Luminescence Investigations of the Nitridomagnesoaluminates Mg3AlnNn+2 with n=1, 2, 3
Eur. J. Inorg. Chem. 2017(20), 2727-2735.
DOI: 10.1002/ejic.201700255
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J. Schneider, C. P. Sindlinger, K. Eichele, H. Schubert, L. Wesemann:
Low-Valent Lead Hydride and Its Extreme Low-Field H-1 NMR Chemical Shift
J. Am. Chem. Soc. 2017, 139(19), 6542-6545.
DOI: 10.1021/jacs.7b01856
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J.-J. Maudrich, C. P. Sindlinger, F. S. W. Aicher, K. Eichele, H. Schubert, L. Wesemann:
Reductive Elimination of Hydrogen from Bis(trimethylsilyl)methyltin Trihydride and Mesityltin Trihydride
Chem. Eur. J. 2017, 23(9), 2192-2200.
DOI: 10.1002/chem.201605317
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D. Schmid, A. Seyboldt, K. Eichele, D. Kunz:
Synthesis of a lithium-cyclopentadienide complex by addition of LiNTf2 to a zwitterionic fulvalene
Dalton Trans. 2017, 46(1), 29-32.
DOI: 10.1039/c6dt03355e
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W. Scherer, P. Meixner, K. Batke, J. E. Barquera-Lozada, K. Ruhland, A. Fischer, G. Eickerling, K. Eichele:
J(Si,H)-Kopplungskonstanten in nicht-klassischen Übergangsmetallsilankomplexen
Angew. Chem. 2016, 128(38), 11846-11850.
DOI: 10.1002/ange.201604001
J(Si,H) Coupling Constants in Nonclassical Transition-Metal Silane Complexes
Angew. Chem. Int. Ed. 2016, 55(38), 11673-11677.
DOI: 10.1002/anie.201604001
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J. Schneider, K. M. Krebs, S. Freitag, K. Eichele, H. Schubert, L. Wesemann:
Intramolecular Tetrylene Lewis Adducts: Synthesis and Reactivity
Chem. Eur. J. 2016, 22(28), 9812-9826.
DOI: 10.1002/chem.201601224
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J. Arras, K. Eichele, B. Maryasin, H. Schubert, C. Ochsenfeld, L. Wesemann:
Intermolecular (119)Sn,(31)P Through-Space Spin-Spin Coupling in a Solid Bivalent Tin Phosphido Complex
Inorg. Chem. 2016, 55(9), 4669-4675.
DOI: 10.1021/acs.inorgchem.6b00573
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M. Krieg, F. Reicherter, P. Haiss, M. Stroebele, K. Eichele, M.-J. Treanor, R. Schaub, H. F. Bettinger:
Aufbau eines intern B3N3-dotierten Nanographenmoleküls
Angew. Chem. 2015, 127 8402-8404.
DOI: 10.1002/ange.201412165
Construction of an Internally B3N3-Doped Nanographene Molecule
Angew. Chem. Int. Ed. 2015, 54(28), 8284-8286.
DOI: 10.1002/anie.201412165
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A. Seyboldt, B. Wucher, S. Hohnstein, K. Eichele, F. Rominger, K. W. Toernroos:
Evidence for the Formation of Anionic Zerovalent Group 10 Complexes as Highly Reactive Intermediates
Organometallics 2015, 34(12), 2717-2725.
DOI: 10.1021/om500836m
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K. M. Krebs, J. Wiederkehr, J. Schneider, K. Eichele, H. Schubert, L. Wesemann:
η3-Allylkoordination an Zinn(II) – Reaktivität gegenüber Alkinen und Benzonitril
Angew. Chem. 2015, 127 5593-5597.
DOI: 10.1002/ange.201500386
η3-Allyl Coordination at Tin(II) – Reactivity towards Alkynes and Benzonitrile
Angew. Chem. Int. Ed. 2015, 54, 5502-5506.
DOI: 10.1002/anie.201500386
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T. Gädt, J.-A. Dimmer, S. Fleischhauer, A. Frank, C. Nickl, T. Wütz, K. Eichele, L. Wesemann:
Oxidation of Germa- and Stanna-closo-dodecaborate
Dalton Trans. 2015, 44, 4726-4731.
DOI: 10.1039/c5dt00099h
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M. Ströbele, K. Eichele, H.-J. Meyer:
Cluster Harvesting in the WBr6–P System
Inorg. Chem. 2015, 54(3), 989–992.
DOI 10.1021/ic502333u
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U. Aygül, H.-J. Egelhaaf, P. Nagel, M. Merz, S. Schuppler, K. Eichele, H. Peisert, T. Chassé, Thomas:
Photodegradation of C-PCPDTBT and Si-PCPDTBT: Influence of the Bridging Atom on the Stability of a Low-Band-Gap Polymer for Solar Cell Application
Chem. Phys. Chem. 2015, 16(2), 428-435.
DOI 10.1002/cphc.201402494
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M. Göhner, F. Herrmann, K. Eichele, H. F. Bettinger, M. Ströbele, N. Kuhn:
Die Strukturchemie der 2-Chalkogeno-1,3,4,5-tetraisopropylimidazoline
Z. Naturforsch. B 2014, 69, 1384–1394.
DOI 10.5560/ZNB.2014-4189
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H. Scheel, J. Wiederkehr, K. Eichele, H. A. Mayer, F. Winter, R. Pöttgen, L. Wesemann:
Dinuclear copper complexes: coordination of Group 14 heteroborates
Dalton Trans. 2014, 43(31), 11867-11876.
DOI 10.1039/c4dt01242a
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J. Henning, K. Eichele, R. F. Fink, L. Wesemann:
Structural and Spectroscopic Characterization of Tin–Tin Double Bonds in Cyclic Distannenes
Organometallics 2014, 33(14), 3904–3918.
DOI 10.1021/om500645b
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N. Dettenrieder, C. O. Hollfelder, L. N. Jende, C. Maichle-Mössmer, R. Anwander:
Half-Sandwich Rare-Earth-Metal Alkylaluminate Complexes Bearing Peripheral Boryl Ligands
Organometallics 2014, 33(7), 1528–1531.
DOI 10.1021/om401163a
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C. Schädle, D. Schädle, K. Eichele, R. Anwander:
Methylaluminium-stabilisierte Seltenerdmetalldihydride
Angew. Chem. 2013, 125(50), 13480–13484.
DOI 10.1002/ange.201306783
Methylaluminum-Supported Rare-Earth-Metal Dihydrides
Angew. Chem. Int. Ed. 2013, 52(50), 13238–13242.
DOI 10.1002/anie.201306783
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J. Arras, K. Eichele, L. Wesemann:
Synthesis and Skeletal Transformations of Trinuclear Palladium and Nickel Phosphido Complexes
Eur. J. Inorg. Chem. 2013(33), 5728–5737.
DOI 10.1002/ejic.201300775
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V. Gierz, A. Seyboldt, C. Maichle-Moessmer, K. W. Toernroos, M. T. Speidel, B. Speiser, K. Eichele, D. Kunz:
Dinuclear coinage-metal complexes of bis(NHC) ligands: structural features and dynamic behavior of a Cu-Cu Complex
Organometallics 2012, 31(22), 7893-7901.
DOI 10.1021/om300544g
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J.-A. Dimmer, M. Hornung, K. Eichele, L. Wesemann:
Selenium adducts of germa- and stanna-closo-dodecaborate: coordination at platinum, structural studies and NMR spectroscopy
Dalton Trans. 2012, 41(29), 8989-8996.
DOI 10.1039/C2DT30478C
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S. Biswas, M. Mueller, C. Toenshoff, K. Eichele, C. Maichle-Moessmer, A. Ruff, B. Speiser, H. F. Bettinger:
The Overcrowded Borazine Derivative of Hexabenzotriphenylene Obtained through Dehydrohalogenation
Eur. J. Org. Chem. 2012(24), 4634-4639.
DOI 10.1002/ejoc.201200322
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J. Henning, H. Schubert, K. Eichele, F. Winter, R. Poettgen, H. A. Mayer, L. Wesemann:
Synthesis and Characterization of N-[2-P(i-Pr)2-4-methylphenyl]2- (PNP) Pincer Tin(IV) and Tin(II) Complexes
Inorg. Chem. 2012, 51(10), 5787-5794.
DOI 10.1021/ic300324s
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C. Toenshoff, M. Mueller, T. Kar, F. Latteyer, T. Chassé, K. Eichele, H. F. Bettinger:
B3N3 Borazine Substitution in Hexa-peri-Hexabenzocoronene: Computational Analysis and Scholl Reaction of Hexaphenylborazine
ChemPhysChem 2012, 13(5), 1173-1181.
DOI 10.1002/cphc.201101025
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C. Nickl, K. Eichele, L. Wesemann:
1,2-Distanna-closo-dodecaborate—a rare example of a 1,2-distannylene ligand in transition metal chemistry
Dalton Trans. 2012, 41, 243-250.
DOI 10.1039/C1DT11247C
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M. Stroebele, K. Eichele, H.-J. Meyer:
Phosphorus-Centered and Phosphinidene-Capped Tungsten Chloride Clusters
Eur. J. Inorg. Chem. 2011, 4063-4068.
DOI 10.1002/ejic.201100122
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K. Eichele, A.-R. Grimmer:
Phosphorus-31 and Vanadium-51 Solid-State Nuclear Magnetic Resonance Spectroscopy of beta-Vanadyl Phosphate — Effects of Homo- and Heteronuclear
Spin-Spin, Electrostatic, and Paramagnetic Interactions
Can. J. Chem. 2011, 89(7), 870-884.
DOI 10.1139/v11-025
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A. Wagenpfeil, C. Nickl, H. Schubert, K. Eichele, M. A. Fox, L. Wesemann:
1,2-Carbagerma-closo-dodecaborate as a Germanium Ligand in Coordination Chemistry – Synthesis, Structure and Reactivity
Eur. J. Inorg. Chem. 2011(22), 3349–3356.
DOI 10.1002/ejic.201100310
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C. Nickl, K. Eichele, D. Joosten, T. Langer, F. M. Schappacher, R. Pöttgen, U. Englert, L. Wesemann, Lars:
1,1,1-Tris(distanna-closo-dodecaborat)stannat – ein tripodaler Zinnligand
Angew. Chem. 2011, 123, 5886-5889.
DOI 10.1002/ange.201100936
1,1,1-Tris(distanna-closo-dodecaborate)stannate: A Tripodal Tin Ligand
Angew. Chem. Int. Ed. 2011, 50, 5766-5769.
DOI 10.1002/anie.201100936
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S. Fleischhauer, K. Eichele, I. Schellenberg, R. Pöttgen, L. Wesemann:
Cobalt, Rhodium, Iridium, and Ruthenium Carbonyl Complexes with Stanna-closo-dodecaborate: 103Rh NMR, 119Sn Mössbauer Spectroscopy, and Solid-State 119Sn NMR
Organometallics 2011, 30, 3200–3209.
DOI 10.1021/om200301v
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H. Schubert, J.-A. Dimmer, F.-R. Küchle, K. Eichele, L. Wesemann:
Homoleptic Coinage Metal Compounds of Group(IV)heteroborates
Inorg. Chem. 2011, 50, 664-670.
DOI 10.1021/ic102118n
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M. Zimmermann, D. Rauschmaier, K. Eichele, K. W. Törnroos, R. Anwander:
Amido-stabilized rare-earth metal mixed methyl methylidene complexes
Chem. Commun. 2010, 46, 5346 - 5348.
DOI 10.1039/c003206a
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C. Nickl, D. Joosten, K. Eichele, C. Maichle-Mössmer, K. W. Törnroos, L. Wesemann:
Synthese und Charakterisierung von Digerma-closo-dodecaborat, einem höheren Homologen des ikosaedrischen ortho-Carborans
Angew. Chem. 2009, 121, 8061-8065.
DOI 10.1002/ange.200903300
Synthesis and Characterization of Digerma-closo-dodecaborate: A Higher Homologue of Icosahedral ortho-Carborane
Angew. Chem. Int. Ed. 2009, 48, 7920-7923.
DOI 10.1002/anie.200903300
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M. Kirchmann, K. Eichele, L. Wesemann:
Synthesis and Characterization of the Platinum(IV) Hydride [PtH(SnB11H11)5]7-
Organometallics 2008, 27, 6029-6031
DOI 10.1021/om8006536
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M. Kirchmann, T. Gaedt, K. Eichele, L. Wesemann:
Nickel coordination compounds of stanna-closo-dodecaborate
Eur. J. Inorg. Chem. 2008, 2261-2265
DOI 10.1002/ejic.200800142
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M. Kirchmann, K. Eichele, L. Wesemann:
Homoleptic Cadmium and Mercury Compounds of Stanna-closo-dodecaborate
Inorg. Chem. 2008, 47, 5988-5991
DOI 10.1021/ic800357z
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M. Kirchmann, K. Eichele, F. M. Schappacher, R. Pöttgen, L. Wesemann:
Oktaedrische Koordinationsverbindungen der Ni, Pd, Pt-Triade
Angew. Chem. 2008, 120, 977-980.
DOI 10.1002/ange.200704814
Octahedral Coordination Compounds of the Ni, Pd, Pt Triad
Angew. Chem. Int. Ed. 2008, 47, 963-966.
DOI 10.1002/anie.200704814
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A. M. Winter, K. Eichele, H.-G. Mack, W. C. Kaska, H. A. Mayer:
Prototropic rearrangements in cycloheptatrienyl PCP pincer iridium complexes.
J. Chem. Soc., Dalton Trans. 2008, 527-532.
DOI 10.1039/b712712j
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K.-P. Zeller, P. Haiss, M. Hartmann, K. Eichele:
Unexpected Course of a Williamson Ether Synthesis.
ARKIVOC 2007, VII, 291-300.
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B. A. Demko, K. Eichele, R. E. Wasylishen:
A Combined Experimental and Quantum Chemistry Study of Selenium Chemical Shift Tensors
J. Phys. Chem. A 2006, 110, 13537-13550.
DOI 10.1021/jp064543s
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N. Kuhn, K. Eichele, M. Steimann, A. Al-Sheikh, B. Doser, C. Ochsenfeld:
Wasserstoffbrückenbindungen mit Cyanidionen? Die Strukturen von
1,3-Diisopropyl-4,5-dimethylimidazoliumcyanid und 1-Isopropyl-3,4,5-trimethylimidazoliumcyanid.
Z. Anorg. Allg. Chem. 2006, 632, 2268-2275.
DOI 10.1002/zaac.200600157
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T. Gädt, K. Eichele, L. Wesemann:
Bimetallic Zwitterionic Complexes with an Ambident Stanna-closo-dodecaborate Ligand:
[1-{M(CO)5}-2,7,8-(m-H)3-{Fe(triphos)}-SnB11H11] (M = Cr, Mo, W)
Organometallics 2006, 25, 3904-3911.
DOI 10.1021/om060328m
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T. Gädt, K. Eichele, L. Wesemann:
Bonding Modes of Stanna-closo-Dodecaborate: h1(Sn) to h3(BH)
Rearrangement Reactions in Zwitterionic Stanna-closo-Dodecaborate Ruthenium Complexes
J. Chem. Soc., Dalton Trans. 2006, 2706-2713.
DOI 10.1039/b517138e
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R. Schmitt, B. Blaschkowski, K. Eichele, H.-J. Meyer:
Calcium Tetraboride-Does It Exist? Synthesis and Properties of a
Carbon-Doped Calcium Tetraboride That Is Isotypic with the Known Rare Earth
Tetraborides
Inorg. Chem. 2006, 45, 3067 -3073.
DOI 10.1021/ic0518430
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T. Gädt, B. Grau, K. Eichele, I. Pantenburg, L. Wesemann:
Ruthenium complexes with the stanna-closo-dodecaborate ligand:
coexistence of h1(Sn) and h3(B-H) coordination
Chem. Eur. J. 2006, 12, 1036-1045.
DOI 10.1002/chem.200500761
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N. Kuhn, A. Abu-Rayyan, A. Al-Sheikh, K. Eichele, C. Maichle-Mößmer, M. Steimann, K. Sweidan:
Zur Strukturchemie von 2-Methylenimidazolinen
Z. Naturforsch. B 2005, 60, 294-299.
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A. M. Winter, K. Eichele, H.-G. Mack, W. C. Kaska, H. A. Mayer:
C-H versus Ir-X (X = H, Cl) Reactivity in a Tropylium PCP Pincer Iridium Complex
Organometallics 2005, 24, 1837-1844.
DOI 10.1021/om049289+
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K. Eichele, C. Nachtigal, S. Jung, H. A. Mayer, E. Lindner, M. Ströbele:
A Simple Molecule with a Complex Crystal Structure: Interplay of 31P Solid-State
NMR Spectroscopy and Single-Crystal X-ray Diffraction in the Structure Determination
of a Ruthenium Diphosphine Diamine Complex.
Magn. Reson. Chem. 2004, 42, 807-813.
DOI 10.1002/mrc.1433
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N. Kuhn, A. Abu-Rayyan, K. Eichele, C. Piludu, M. Steimann:
Weak Interionic Interactions in 2-Haloimidazolium Hexahalotellurates(IV)
Z. Anorg. Allg. Chem. 2004, 630, 495-497.
DOI 10.1002/zaac.200300401
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I. Warad, K. Eichele, H. A. Mayer, E. Lindner:
Supported organometallic complexes part 39: cationic diamine(ether–phosphine)ruthenium(II)
complexes as precursors for the hydrogenation of trans-4-phenyl-3-butene-2-one
Inorg. Chim. Acta 2004, 357, 1847-1853.
DOI 10.1016/j.ica.2003.12.015
-
N. Kuhn, A. Abu-Rayyan, K. Eichele, S. Schwarz, M. Steimann:
Weak interionic interactions in 2-bromoimidazolium derivatives.
Inorg. Chim. Acta 2004, 357, 1799-1804.
DOI 10.1016/j.ica.2003.10.038
-
A. M. Winter, K. Eichele, H.-G. Mack, S. Potuznik, H. A. Mayer, W. C. Kaska:
Rhodium pincer complexes of 2,2'-bis(diphenylphosphino)diphenylamine
J. Organomet. Chem. 2003, 682, 149-154.
DOI 10.1016/S0022-328X(03)00776-9
-
E. Lindner, M. Henes, W. Wielandt, K. Eichele, M. Steimann, G. A. Luinstra, H.-H. Görtz:
Transition metal-catalyzed polymerization of 1,3,5-trioxane
J. Organomet. Chem. 2003, 681, 12-23
DOI 10.1016/S0022-328X(03)00527-8
-
D. L. Bryce, K. Eichele, R. E. Wasylishen:
An 17O NMR and Quantum Chemical Study of Monoclinic and Orthorhombic Polymorphs of
Triphenylphosphine Oxide.
Inorg. Chem. 2003, 42, 5085-5096.
DOI 10.1021/ic020706p
-
Z.-L. Lu, K. Eichele, I. Warad, H. A. Mayer, E. Lindner, Z.-j. Jang, V. Schurig:
Supported Organometallic Complexes. XXXVIII. Bis(methoxyethyldimethylphosphine)ruthenium(II)
Complexes as Transfer Hydrogenation Catalysts
Z. Anorg. Allg. Chem. 2003, 629, 1308-1315.
DOI 10.1002/zaac.200300067
-
E. Lindner, I. Warad, K. Eichele, H. A. Mayer:
Supported organometallic complexes Part 34: synthesis and structures
of an array of diamine(ether-phosphine)ruthenium(II) complexes and
their application in the catalytic hydrogenation of
trans-4-phenyl-3-butene-2-one.
Inorg. Chim. Acta 2003, 350, 49-56.
DOI 10.1016/S0020-1693(02)01535-9
-
E. Lindner, R. Zong, M. Ströbele, K. Eichele:
Preparation, properties, and reactions of metal-containing heterocycles.
CX. 1. Crystal structure of 1,1'-bis{[4-(1,10-phenanthroline-3-yl-ethynyl)-
2,5-dipropoxy-phenyl]ethynyl}ferrocene.
Z. Anorg. Allg. Chem. 2003, 629, 587-588.
DOI 10.1002/zaac.200390097
-
E. Lindner, R. F. Zong, K. Eichele, U. Weisser, M. Ströbele:
Preparation, properties, and reactions of metal-containing heterocycles, 109.
Synthesis and structure of redox-active heterotetranuclear molecular polygons
by self-assembly of two ferrocene-bridged bis(pyridines) with two transition
metals
Eur. J. Inorg. Chem. 2003, 705-712.
DOI 10.1002/ejic.200390097
-
Z.-L. Lu, K. Eichele, E. Lindner, H. A. Mayer:
Supported organometallic complexes. Part 37: Synthesis and structures of
diamine-bis(methoxyethyldimethylphosphine) ruthenium(II) complexes.
Inorg. Chem. Commun. 2003, 6, 365 –369.
DOI 10.1016/S1387-7003(02)00774-8
-
E. Lindner, H. A. Mayer, I. Warad, K. Eichele:
Supported organometallic complexes. Part XXXV. Synthesis, characterization,
and catalytic application of a new family of diamine(diphosphine)ruthenium(II)
complexes
J. Organomet. Chem. 2003, 665, 176-185.
DOI 10.1016/S0022-328X(02)02112-5
-
H. A. Y. Mohammad, J. C. Grimm, K. Eichele, H.-G. Mack, B. Speiser, F. Novak, M. G. Quintanilla,
W. C. Kaska, H. A. Mayer:
C-H Oxidative Addition with a (PCP)Ir(III)-Pincer Complex
Organometallics 2002, 21, 5775-5784.
DOI 10.1021/om020621w
-
E. Lindner, R. F. Zong, K. Eichele, M. Ströbele:
Preparation, properties, and reactions of metal-containing heterocycles Part CVIII. A novel
generation of rigid, nanoscaled 1,1'-ferrocenediyl-bridged bis(pyridine), bis(bipyridine),
and bis(phenanthroline) ligands
J. Organomet. Chem. 2002, 660, 78-84.
DOI 10.1016/S0022-328X(02)01774-6
-
E. Lindner, C. S. Ayasse, K. Eichele, M. Steimann:
Macrocyclic Di- and Tetranuclear Osmacycloferrocenophanes.
Organometallics 2002, 21, 4217-4225.
DOI 10.1021/om020310l
-
N. Kuhn, K. Eichele, M. Walker, Th. Berends, R. Minkwitz:
Neuartige elementorganische Sauerstoffsäuren des Phosphors und Schwefels [1]
Z. Anorg. Allg. Chem. 2002, 628, 2026-2032.
DOI 10.1002/1521-3749(200209)628:9/10<2026::AID-ZAAC2026>3.0.CO;2-0
-
K. Eichele, R. E. Wasylishen, J. F. Corrigan, N. J. Taylor, A. J. Carty,
K. W. Feindel, G. M. Bernard:
Phosphorus Chemical Shift Tensors of Phosphido Ligands in Ruthenium Carbonyl
Compounds: 31P NMR Spectroscopy of Single-Crystal and Powder Samples and ab initio Calculations.
J. Am. Chem. Soc. 2002, 124, 1541-1552.
DOI 10.1021/ja0122041
-
C. Nachtigal, S. Al-Gharabli, K. Eichele, E. Lindner, H. A. Mayer:
Structural Studies of an Array of Mixed Diamine Phosphine Ruthenium(II) Complexes
Organometallics 2002, 21, 105-112.
DOI 10.1021/om0105831
-
D. L. Bryce, G. M. Bernard, M. Gee, M. D. Lumsden, K. Eichele, R. E. Wasylishen:
Practical Aspects of Modern Routine Solid-State Multinuclear Magnetic Resonance Spectroscopy:
One-Dimensional Experiments.
Can. J. Anal. Sci. Spectrosc. 2001, 46, 46-82.
For a "reprint", see this page!
-
B. Thomas, S. Paasch, S. Steuernagel, K. Eichele:
Residual 31P, 35,37Cl Dipolar Coupling in 31P MAS Spectra of
Chlorocyclophosphazenes.
Solid State Nucl. Magn. Reson. 2001, 20, 108-117.
DOI 10.1006/snmr.2001.0034
-
N. Kuhn, K. Eichele, M. Walker:
Synthesis and Structure of 1,3-Diisopropyl-4,5-dimethylimidazolium-2-sulfonate:
A Carbene Adduct of Sulfur Trioxide.
Z. Anorg. Allg. Chem. 2001, 627, 2565-2567.
DOI 10.1002/1521-3749(200112)627:12<2565::AID-ZAAC2565>3.0.CO;2-I
-
S. Schweizer, K. Eichele, H. P. T. Ammon, H. Safayhi:
3-Acetoxy Group of Genuine AKBA (Acetyl-11-keto-b-boswellic Acid) is
a-Configurated.
Planta Medica 2000, 66, 781-782.
DOI 10.1055/s-2000-9614
-
G. M. Bernard, K. Eichele, G. Wu, C. Kirby, R. E. Wasylishen:
Nuclear Magnetic Shielding Tensors for the Carbon, Nitrogen and Selenium Nuclei of
Selenocyanates—A Combined Experimental and Theoretical Approach.
Can. J. Chem. 2000, 78, 614-625.
-
E. Lindner, J. Wald, K. Eichele, R. Fawzi:
Synthesis, structure, and reactivity of ruthenium(II) complexes with a hemilabile
tetradentate etherdiphosphine ligand.
J. Organomet. Chem. 2000, 601, 220-225.
DOI 10.1016/S0022-328X(00)00065-6
-
M. Gee, R. E. Wasylishen, K. Eichele, J. F. Britten:
Phosphorus Chemical Shift Tensors for Tetramethyldiphosphine Disulfide - A
31P Single-Crystal NMR, Dipolar-Chemical Shift NMR and Ab Initio Molecular Orbital Study.
J. Phys. Chem. A 2000, 104, 4598-4605.
DOI 10.1021/jp9944839
- M. Gee, R. E. Wasylishen, K. Eichele, G. Wu, T. S. Cameron, F. Mathey, F. Laporte:
Characterization of Phosphorus Chemical Shielding Tensors in a Phosphole Tetramer:
A Combined Experimental and Theoretical Study.
Can. J. Chem. 2000, 78, 118-127.
- K. Eichele, G. Ossenkamp, R. E. Wasylishen, T. S. Cameron, J. F. Britten:
Phosphorus-31 Solid-State NMR Studies of Homonuclear Spin Pairs in Molybdenum Phosphine
Complexes: Single-Crystal, Dipolar-Chemical Shift, Rotational-Resonance and 2D Spin-Echo
NMR Experiments
Inorg. Chem. 1999, 38, 639-651.
DOI 10.1021/ic9806232
- K. Eichele, R. E. Wasylishen, J. H. Nelson:
Solid-State 95Mo NMR Studies of Some Prototypal Molybdenum Compounds: Sodium
Molybdate Dihydrate, Hexacarbonylmolybdenum, and Pentacarbonyl Phosphine
Molybdenum (0) Complexes.
J. Phys. Chem. A 1997, 101, 5463-5468.
DOI 10.1021/jp9712415
- K. Eichele, R.E. Wasylishen, K. Maitra, J.H. Nelson, J.F. Britten:
Single-Crystal 31P NMR and X-ray Diffraction Study of a Molybdenum Phosphine
Complex: (5-Methyldibenzophosphole)pentacarbonylmolybdenum(0).
Inorg. Chem. 1997, 36, 3539-3544.
DOI 10.1021/ic970260q
- K. Eichele, J.C.C. Chan, R.E. Wasylishen, J.F. Britten:
Single-Crystal Cobalt-59 NMR Study of Tris(2,4-pentanedionato-O,O') Cobalt(III).
J. Phys. Chem. A 1997, 101, 5423-5430.
DOI 10.1021/jp970370i
- S. Kroeker, K. Eichele, R.E. Wasylishen, J.F. Britten:
Cesium-133 NMR Study of CsCd(SCN)3: Relative Orientation of the Chemical Shift and
Electric Field Gradient Tensors.
J. Phys. Chem. B 1997, 101, 3727-3733.
DOI 10.1021/jp970043a
- K.V. Ramanathan, N. Suryaprakash, C.L. Khetrapal, E.D. Becker, K. Eichele and R.E. Wasylishen:
13C MAS NMR Spectra of cis,cis-Mucononitrile in Liquid Crystalline Media and the Solid
State - Orientation of the Carbon Chemical Shift Tensors
J. Magn. Reson. Ser. A 1996, 123, 196-200.
DOI 10.1006/jmra.1996.0235
- K. Eichele, R.E. Wasylishen, R.W. Schurko, N. Burford, and W.A. Whitla:
An Unusually Large Value of 1J(31P,31P) for a Solid
Triphenyphoshine Phoshadiazonium Cationic Complex: Determination of the Sign of J from 2D Spin-Echo
Experiments
Can. J. Chem. 1996, 74, 2372-2377.
- N. Burford, T.S. Cameron, J.A.C. Clyburne, K. Eichele, K.N. Robertson, S. Sereda, R.E. Wasylishen and W.A. Whitla:
Nucleophilic Addition of CH, NH, and OH Bonds to the Phosphadiazonium Cation and Interpretation of 31P
Chemical Shifts at Dicoordinate Phosphorus Centers.
Inorg. Chem. 1996, 35, 5460-5467.
DOI 10.1021/ic960131u
- K. Eichele, R.E. Wasylishen, J.M. Kessler, L. Solujic and J.H. Nelson:
Phosphorus Chemical Shift Tensors of Phosphole Derivatives Determined by 31P NMR Spectroscopy of Powder
Samples.
Inorg. Chem. 1996, 35, 3904-3912.
DOI 10.1021/ic960095z
- W.L. Wilson, J. Fischer, R.E. Wasylishen, K. Eichele, V.J. Catalano, J.H. Frederick and J.H. Nelson:
Thermal Coupling Reactions of 1-Phenyl-3,4-dimethylphosphole within the Coordination Sphere of Palladium (II).
Inorg. Chem. 1996, 35, 1486-1496.
DOI 10.1021/ic951307f
-
I.V. Kourkine, M.B. Chapman, D.S. Glueck, K. Eichele, R.E. Wasylishen, G.P.A. Yap, L.M. Liable-Sands and A.L. Rheingold:
Synthesis and Ligand Substitution Reactions of a Mesitylphosphido-Bridged Platinum(II) Dimer.
Inorg. Chem. 1996, 35, 1478-1485.
DOI 10.1021/ic951020i
-
G. Wu, M.D. Lumsden, G.C. Ossenkamp, K. Eichele and R.E. Wasylishen:
Carbonyl carbon chemical shift tensors for a typical aryl aldehyde and formaldehyde. NMR studies of the isolated 13C-2H spin pair of 3,4-dibenzyloxybenaldehyde-13Ca,2Ha.
J. Phys. Chem. 1995, 99, 15806-15813.
DOI 10.1021/j100043a019
-
K. Eichele, R. E. Wasylishen, J. F. Corrigan, N. J. Taylor, A. J. Carty:
Phosphorus-31 Chemical Shift Tensors of Phosphinidene Ligands in Ruthenium Carbonyl Cluster Compounds: A 31P Single-Crystal and CP/MAS NMR Study.
J. Am. Chem. Soc. 1995, 117, 6961-6969.
DOI 10.1021/ja00131a019
-
K. Eichele, S. Kroeker, G. Wu, R. E. Wasylishen:
Set-up Samples for 199Hg CP/MAS NMR Spectroscopy.
Solid State Nucl. Magn. Reson. 1995, 4, 295-300.
DOI 10.1016/0926-2040(95)00015-I
-
K. Eichele, R. E. Wasylishen, J. S. Grossert, A. C. Olivieri:
The Influence of Chlorine-Carbon Dipolar and Indirect Spin-Spin Interactions on High-Resolution Carbon-13 NMR Spectra of Chloroketosulfones in the Solid State.
J. Phys. Chem. 1995, 99, 10110-10113.
DOI 10.1021/j100025a010
-
K. Eichele, G. Wu, R. E. Wasylishen, J. F. Britten:
Phosphorus-31 NMR Studies of Solid Tetraethyldiphosphine Disulfide.
A Reinvestigation of the 31P,31P Spin-Spin Coupling Tensor.
J. Phys. Chem. 1995, 99, 1030-1037.
DOI 10.1021/j100003a028
-
G. Wu, K. Eichele, R. E. Wasylishen:
Magic-Angle Spinning Frequency Dependent NMR Spectra Arising from
a Pair of Crystallographically Equivalent Phosphorus Nuclei.
In: "Phosphorus-31 NMR Spectral Properties in Compound Characterization
and Structural Analysis"; L. D. Quin, J. G. Verkade (Eds.);
VCH Publishers,
1994, pp 441-450.
-
M. D. Lumsden, K. Eichele, R. E. Wasylishen, T. S. Cameron,
J. F. Britten:
Determination of a 199Hg-31P Indirect Spin-Spin Coupling Tensor
via Single-Crystal Phosphorus NMR Spectroscopy.
J. Am. Chem. Soc. 1994, 116, 11129-11136.
DOI 10.1021/ja00103a030
-
K. Eichele, R. E. Wasylishen:
High-Resolution 113Cd CP/MAS NMR Studies of Cadmium Thiocyanate
Coordination Compounds. Direct Observation of 113Cd,14N Spin-Spin
Coupling Constants in the Solid State.
Inorg. Chem. 1994, 33, 2766-2773.
DOI 10.1021/ic00091a017
-
K. Eichele, R. E. Wasylishen:
A 31P NMR Study of Powder and Single-Crystal Samples of Ammonium
Dihydrogen Phosphate: The Effect of Homonuclear Dipolar Coupling.
J. Phys. Chem. 1994, 98, 3108-3113.
DOI 10.1021/j100063a012
-
M. D. Lumsden, R. E. Wasylishen, K. Eichele, M. Schindler,
G. H. Penner, W. P. Power, R. D. Curtis:
The Carbonyl Carbon and Nitrogen Chemical Shift Tensors of the
Amide Fragment of Acetanilide and N-Methylacetanilide.
J. Am. Chem. Soc. 1994, 116, 1403-1413.
DOI 10.1021/ja00083a028
Looking for information on acetanilide? Check out my "NMR of acetanilide" page!
-
R. E. Wasylishen, K. C. Wright, K. Eichele, T. S. Cameron:
Characterization of the J(115In,31P) Tensor for a 1:1 Adduct of
Indium Tribromide and a Triarylphosphine.
Inorg. Chem. 1994, 33, 407-408.
DOI 10.1021/ic00081a003
-
K. Eichele, R. E. Wasylishen:
The Dipolar Splitting Ratio Method - A Convenient Approach to the
Analysis of Dipolar-Chemical Shift NMR Spectra of Static Powder
Samples.
J. Magn. Reson. A 1994, 106, 46-56.
DOI 10.1006/jmra.1994.1005
-
K. L. Moran, T. E. Grier, W. T. A. Harrison, G. D. Stucky, H. Eckert,
K. Eichele, R. E. Wasylishen:
Synthesis and Characterization of Mixed ZnSe/GaP Semiconductor
Species Included in the Sodalite Structure.
J. Am. Chem. Soc. 1993, 115, 10553-10558.
DOI 10.1021/ja00076a013
-
K. Eichele, M. D. Lumsden, R. E. Wasylishen:
Nitrogen-14 Coupled Dipolar-Chemical Shift 13C NMR Spectra of the
Amide Fragment of Peptides in the Solid State.
J. Phys. Chem. 1993, 97, 8909-8916.
DOI 10.1021/j100137a014
Errata: unfortunately, there is a sign error in eq. (10), the last term should have a positive sign!
-
K. Eichele, R. E. Wasylishen, J. F. Corrigan, S. Doherty, Y. Sun,
A. J. Carty:
Observations of 1J(P,Ru) in 31P CP/MAS NMR Spectra of Solid
Ruthenium Compounds.
Inorg. Chem. 1993, 32, 121-123.
DOI 10.1021/ic00054a001
-
K. Eichele, G. Wu, R. E. Wasylishen:
Unusual "AB" Spectra in High-Resolution Magic-Angle Spinning
NMR Studies of Solids.
J. Magn. Reson. 1993, A101, 157-161.
DOI 10.1006/jmra.1993.1025
-
K. Eichele, R. E. Wasylishen:
Experimental Characterization of 31P Chemical Shift Tensors in
Phosphine Derivatives.
In: "Nuclear Magnetic Shieldings and Molecular Structure";
J. A. Tossell (Ed.); NATO ASI Series Vol. 386C, p 563,
Kluwer Academic Publishers, Dordrecht 1993.
-
R. E. Wasylishen, R. D. Curtis, K. Eichele, M. D. Lumsden,
G. H. Penner, W. P. Power, G. Wu:
Applications of Dipolar NMR Spectroscopy in Characterizing
Nitrogen and Phosphorus Shielding Tensors.
In: "Nuclear Magnetic Shieldings and Molecular Structure";
J. A. Tossell (Ed.); NATO ASI Series Vol. 386C, pp 297-314,
Kluwer Academic Publishers, Dordrecht 1993.
-
K. Eichele, R. E. Wasylishen:
Indirect 113Cd,14N Spin-Spin Coupling Constants as a Structural
Probe of Solid Cadmium Thiocyanate Complexes.
Angew. Chem. 1992, 104, 1263-1265;
DOI 10.1002/ange.19921040935
Angew. Chem., Int. Ed. Engl. 1992, 31, 1222-1224.
DOI 10.1002/anie.199212221
-
K. Eichele, R. E. Wasylishen:
Observation of nitrogen-14, carbon-13 indirect spin-spin coupling
in high-resolution 13C CP/MAS spectra of solids.
Solid State Nucl. Magn. Reson. 1992, 1, 159-163.
DOI 10.1016/0926-2040(92)90016-3
-
E. Lindner, R. Fawzi, H. A. Mayer, K. Eichele, W. Hiller:
Effect of Ring Size on NMR Parameters: Cyclic Bisphosphine Complexes
of Molybdenum, Tungsten, and Platinum. Bond Angle Dependence of Metal
Shieldings, Metal-Phosphorus Coupling Constants, and the 31P Chemical
Shift Anisotropy in the Solid State.
Organometallics 1992, 11, 1033-1043.
DOI 10.1021/om00039a007
-
K. Eichele:
Beziehungen zwischen Struktur- und NMR-Parametern von Phosphor-
Verbindungen in Loesung und im Festkoerper.
Ph. D. Thesis, University of Tuebingen 1991.
-
E. Lindner, R. Fawzi, H. A. Mayer, K. Eichele, K. Pohmer:
Phosphorus-31 Solid-State NMR Studies of Cyclic and Acyclic
Phosphine-Metal Complexes. Determination of Chemical Shift Anisotropy,
Scalar Coupling 1J(M-P) (M = 55Mn, 95/97Mo, 183W), and 55Mn
Quadrupolar Coupling Constants.
Inorg. Chem. 1991, 30, 1102-1107.
DOI 10.1021/ic00005a041
-
E. Lindner, M. Pabel, K. Eichele:
Synthese alkylenverbrueckter Metallkomplexe nach der kationischen
Alkylierung mit Alkandiylbis(trifluormethansulfonaten).
J. Organomet. Chem. 1990, 386, 187-194.
DOI 10.1016/0022-328X(90)85243-R
-
E. Lindner, R. Fawzi, H. A. Mayer, K. Eichele, K. Pohmer:
Darstellung und Eigenschaften von und Reaktionen mit metallhaltigen
Heterocyclen. LXX. Untersuchungen ueber den Zusammenhang zwischen
Konformation und chemischer Verschiebung in
Phosphametallacycloalkanen.
J. Organomet. Chem. 1990, 386, 63-77.
DOI 10.1016/0022-328X(90)80257-Z
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