[Uni Tübingen] - [Mat.-Nat. Fakultät] - [Fachbereich Chemie] - [Anorg. Chemie] - [AK Wesemann] - Publikationen

Publikationen Lars Wesemann

Inhalt [2019] [2018] [2017] [2016] [2015] [2014] [2013] [2012] [2011] [2010] [2009] [2008] [2007] [2006] [2005] [2004] [2003] [2002] [2001] [2000] [1999] [1997] [1996] [1995] [1993] [1992] [1991] [1990]

    --- 2019 --- [UP]

  1. D. Raiser, C. P. Sindlinger, H. Schubert, L. Wesemann:
    Ge=B π-bonding: Synthesis and Reversible [2+2] Cycloaddition of Germaborenes,
    Angew. Chem. Int. Ed. In press. DOI: 10.1002/anie.201914608
  2. J.-J. Maudrich, M. Widemann, F. Diab, R. H. Kern, P. Sirsch, C. P. Sindlinger, H. Schubert, L. Wesemann:
    Hydridoorganostannylene coordination - Group 4 metallocene dichloride reduction in reaction with organodihydridostannate anions,
    Chem. Eur. J. 2019, 25, 16081-16087. DOI: 10.1002/chem.201903652
  3. S. Weiß, H. Schubert, L. Wesemann:
    Low valent lead hydride chemistry: hydroplumbylation of phenylacetylene and 1,1-dimethylallene,
    Chem. Commun. 2019, 55, 10238-10240. DOI: 10.1039/C9CC05431F
  4. J.-J. Maudrich, F. Diab, S. Weiß, M. Widemann, T. Dema, K. Eichele, H. Schubert, L. Wesemann:
    Deprotonation of Organogermanium and Organotin Trihydrides,
    Inorg. Chem. 2019, 58, 15758-15768. DOI: 10.1021/acs.inorgchem.9b01822
  5. K. M. Krebs, D. Hanselmann, H. Schubert, K. Wurst, M. Scheele, L. Wesemann:
    Phosphine-Stabilized Digermavinylidene,
    J. Am. Chem. Soc. 2019, 141, 3424-3429. DOI: 10.1021/jacs.8b13645
  6. F. Diab, F. S. W. Aicher, C. P. Sindlinger, K. Eichele, H. Schubert, L. Wesemann:
    Reductive Elimination and Oxidative Addition of Hydrogen at Organostannylium and Organogermylium Cations,
    Chem. Eur. J. 2019, 25, 4426-4434. DOI: 10.1002/chem.201805770
  7. S. Weiß, M. Auer, K. Eichele, H. Schubert, L. Wesemann:
    η3-Allyl Coordination at Pb(II),
    Organometallics 2019, 38, 417-423. DOI: 10.1021/acs.organomet.8b00766
  8. --- 2018 --- [UP]

  9. F. S. W. Aicher, K. Eichele, H. Schubert, L. Wesemann:
    Complete Hydrogen Transfer: Tin Hydride Reactivity toward Adamantylisonitrile and Benzonitrile,
    Organometallics 2018, 37, 1773-1780, DOI: 10.1021/acs.organomet.8b00207
  10. J. Henoch, A. Auch, F. Diab, K. Eichele, H. Schubert, P. Sirsch, T. Block, R. Pöttgen, L. Wesemann:
    Cyclic Distannene or Bis(stannylene) with a Ferrocenyl Backbone - Synthesis, Structure and Coordination Chemistry,
    Inorg. Chem. 2018, 57, 4135-4145. DOI: 10.1021/acs.inorgchem.8b00317
  11. K. M. Krebs, S. Freitag, J.-J. Maudrich, H. Schubert, P. Sirsch, L. Wesemann:
    Coordination Chemistry of Stannylene-Based Lewis pairs - Insertion into M-Cl and M-C bonds. From base stabilized stannylenes to bidentate ligands,
    Dalton Trans. 2018, 47, 83-95, DOI: 10.1039/C7DT04044J
  12. --- 2017 --- [UP]

  13. T. Wütz, L. Wesemann:
    Synthesis and coordination chemistry of a P-Sn-chelating ligand based on stanna-closo-dodecaborate,
    Eur. J. Inorg. Chem. 2017, 4645-4652, DOI: 10.1002/ejic.201700471
  14. J. Schneider, C. P. Sindlinger, K. Eichele, H. Schubert, L. Wesemann:
    A low-valent lead hydride and its extreme low-field 1H NMR chemical shift,
    J. Am. Chem. Soc. 2017, 139, 6542-6545, DOI: 10.1021/jacs.7b01856
  15. C. P. Sindlinger, F. S. W. Aicher, H. Schubert, L. Wesemann:
    Reductive Dehydrogenation of a Stannane via Multiple Sn-H activation by Frustrated Lewis-Pairs,
    Angew. Chem. Int. Ed. 2017, 56, 2198-2202, DOI: 10.1002/anie.201610254
  16. J.-J. Maudrich, C. P. Sindlinger, F. S. W. Aicher, K. Eichele, H. Schubert, L. Wesemann:
    Reductive Elimination of Hydrogen from Bis(trimethylsilyl)methyltin Trihydride and Mesityltin Trihydride,
    Chem. Eur. J. 2017, 23, 2192-2200, DOI: 10.1002/chem.201605317
  17. C. P. Sindlinger, F. S. W. Aicher, L. Wesemann:
    Cationic Stannylenes: in situ-Generation and NMR-spectroscopic characterisation,
    Inorg. Chem. 2017, 56, 548–560. DOI: 10.1021/acs.inorgchem.6b02377
  18. J. Schneider, C. P. Sindlinger, S. M. Freitag, H. Schubert, L. Wesemann:
    Diverse Activation Modes in the Hydroboration of Aldehydes and Ketones with Germanium, Tin and Lead Lewis pairs,
    Angew. Chem. 2017, 129(1), 339-343. DOI: 10.1002/ange.201609155
    Angew. Chem. Int. Ed. 2017, 56, 333-337. DOI: 10.1002/anie.201609155
  19. --- 2016 --- [UP]

  20. J. Schneider, K. M. Krebs, S. Freitag, K. Eichele, H. Schubert, L. Wesemann:
    Intramolecular Tetrylene Lewis adducts: Synthesis and Reactivity,
    Chem. Eur. J. 2016, 22, 9812-9826. DOI: 10.1002/chem.201601224
  21. J. Arras, K. Eichele, B. Maryasin, H. Schubert, C. Ochsenfeld, L. Wesemann:
    Intermolecular 119Sn,31P Through-Space Spin-Spin Coupling in a Solid Bivalent Tin Phosphido Complex,
    Inorg. Chem. 2016, 22, 7554-7566. DOI: 10.1021/acs.inorgchem.6b00573
  22. K. M. Krebs, J.-J. Maudrich, L. Wesemann:
    Reaction of Stannylene Phosphorus Lewis Pairs with Dichlorides of Germanium, Tin and Lead – Formation of Base stabilized Stannyl Stannylenes/Germylenes and Redox Reaction with PbCl2,
    Dalton. Trans. 2016, 45, 8081–8088, DOI: 10.1039/C6DT00916F
  23. C. P. Sindlinger, W. Grahneis, F. S. W. Aicher, L. Wesemann:
    Access to base adducts of low-valent organotin hydride compounds by controlled, stepwise hydrogen abstraction from a tetravalent organotin trihydride,
    Chem. – Eur. J. 2016, 22, 7554-7566, DOI: 10.1002/chem.201505081
  24. K. M. Krebs, J. Jamin and L. Wesemann:
    Reaction of an Allylstannylene with Adamantyl Phosphaalkyne,
    Dalton Trans. 2016, 45, 5933–5936. DOI: 10.1039/C5DT03792A
  25. --- 2015 --- [UP]

  26. J. Arras, H. Speth, H. A. Mayer, L. Wesemann:
    Different Coordination Modes of the Ph2PC(sp3)PPh2 Pincer Ligand in Rhodium Complexes as a Consequence of sp3-C-H Metal Interaction,
    Organometallics 2015, 34, 3629-3636. DOI: 10.1021/acs.organomet.5b00437
  27. C. P. Sindlinger, L. Wesemann:
    Dimeric platinum-stannylene complexes by twofold ligand transfer from an NHC adduct to an organotin(II) hydride,
    Chem. Commun. 2015, 51, 11421-11424. DOI: 10.1039/C5CC03425F
  28. J. Schneider, J. Henning, J. Edrich, H. Schubert, L. Wesemann:
    Reversibility in reactions of linker-bridged distannenes with terminal alkynes at ambient temperature,
    Inorg. Chem. 2015, 54, 6020-6027. DOI: 10.1021/acs.inorgchem.5b00896
  29. C. P. Sindlinger, A. Stasch, H. F. Bettinger L. Wesemann:
    A nitrogen-base catalyzed generation of organotin(II) hydride from an organotin trihydride under reductive dihydrogen elimination,
    Chem. Sci. 2015, 6, 4737–4751. DOI: 10.1039/C5SC01561H
  30. K. M. Krebs, J. Wiederkehr, J. Schneider, K. Eichele, H. Schubert, L. Wesemann:
    η3-Allyl Coordination at Tin(II) – Reactivity towards Alkynes and Benzonitrile,
    Angew. Chem. 2015, 127, 5593-5597. DOI: 10.1002/ange.201500386
    Angew. Chem. Int. Ed. 2015, 54, 5502-5506. DOI: 10.1002/anie.201500386
  31. T. Gädt, J.-A. Dimmer, S. Fleischhauer, A. Frank, C. Nickl, T. Wütz, K. Eichele, L. Wesemann:
    Oxidation of Germa- and Stanna-closo-dodecaborate,
    Dalton Trans. 2015, 44, 4726-4731. DOI: 10.1039/c5dt00099h
  32. K. M. Krebs, S. Freitag, H. Schubert, B. Gerke, R. Pöttgen, L. Wesemann:
    Chemistry of stannylene based Lewis pairs: dynamic tin coordination switching between donor and acceptor character,
    Chem. Eur. J. 2015, 4628-4638. DOI: 10.1002/chem.201406486
  33. C. P. Sindlinger, S. Weiß, H. Schubert, L. Wesemann:
    Nickel triad complexes of a side-on coordinating distannene,
    Angew. Chem. 2015, 127, 4160-4164. DOI: 10.1002/ange.201411025
    Angew. Chem. Int. Ed. 2015, 54, 4087-4091. DOI: 10.1002/anie.201411025
  34. --- 2014 --- [UP]

  35. J. Henning, K. Eichele, R. F. Fink, L. Wesemann:
    Structural and Spectroscopic Characterization of Tin–Tin Double Bonds in Cyclic Distannenes
    Organometallics 2014, 33, 3904–3918. DOI: 10.1021/om500645b
  36. H. Scheel, J. Wiederkehr, K. Eichele, H. A. Mayer, F. Winter, R. Pöttgen, L. Wesemann:
    Dinuclear copper complexes: coordination of Group 14 heteroborates
    Dalton Trans. 2014, 43, 11867–11876. DOI: 10.1039/C4DT01242A
  37. C. P. Sindlinger and L. Wesemann:
    Hydrogen abstraction from organotin di- and trihydrides by N-heterocyclic carbenes: a new method for the preparation of NHC adducts to tin(II) species and observation of an isomer of a hexastannabenzene derivative [R6Sn6]
    Chem. Sci. 2014, 5, 2739–2746. DOI: 10.1039/C4SC00365A
  38. H. Schubert, W. Leis, H. A. Mayer and L. Wesemann:
    A bidentate boryl ligand: syntheses of platinum and iridium complexes
    Chem. Commun. 2014, 50, 2738–2740. DOI: 10.1039/C4CC00344F
  39. C. P. Sindlinger, A. Stasch, L. Wesemann: Heavy Group 15 Element Compounds of a Sterically Demanding Bis(iminophosphorane)methanide and Methandiide
    Organometallics 2014, 33, 322–328. DOI: 10.1021/om401059x
  40. --- 2013 --- [UP]

  41. J. Arras, K. Eichele, L. Wesemann:
    Synthesis and Skeletal Transformations of Trinuclear Palladium and Nickel Phosphido Complexes
    Eur. J. Inorg. Chem. 2013, 5728-5737. DOI: 10.1002/ejic.201300775
  42. S. Freitag, K. M. Krebs, J. Henning, J. Hirdler, H. Schubert, L. Wesemann:
    Stannylene-based Lewis Pairs
    Organometallics 2013, 32, 6785-6791. DOI: 10.1021/om400736e
  43. M. Leitl, F. R. Küchle, H. A. Mayer, L. Wesemann, H. Yersin:
    Brightly Blue and Green Emitting Cu(I) Dimers for Singulet Harvesting in OLEDs
    J. Phys. Chem. A 2013, 117(46), 11823–11836. DOI: 10.1021/jp402975d
  44. M. Stickel, C. Maichle-Moessmer, L. Wesemann, H. A. Mayer:
    Bis(phosphinomethyl)phenylamines and bis(phosphinomethyl)sulfides and their reaction with d8-platinum group precursors
    Polyhedron 2013, 52, 1471–1480. DOI: 10.1016/j.poly.2013.02.001
  45. S. Freitag, J. Henning, H. Schubert, L. Wesemann:
    Phosphastannirane: A Phosphorus/Tin(II) Lewis Pair that Undergoes Alkyne and Alkene Addition
    Angew. Chem. 2013, 125(21), 5750–5754. DOI: 10.1002/ange.201301153;
    Angew. Chem. Int. Ed. 2013, 52(21), 5640–5643. DOI: 10.1002/anie.201301153.
  46. T. Wütz, S. Fleischhauer, L. Wesemann:
    B-N bond formation at stanna-closo-dodecaborate,
    Dalton Trans. 2013(42), 753–758. DOI: 10.1039/C2DT31749D
  47. --- 2012 --- [UP]

  48. J. A. Dimmer, M. Hornung, T. Wütz, L. Wesemann:
    Germa- and Stanna-closo-dodecaborate in Reaction with [PdCl2(Xantphos)]: P–C and B–H Bond Activation,
    Organometallics, 2012, 31, 7044–7051. DOI: 10.1021/om300438x
  49. J. Henning, L. Wesemann:
    Side-on Coordinating Distannene – An Unprecedented Nickel(0) Complex
    Angew. Chem. 2012, 124(51), 13041–13045, DOI: 10.1002/ange.201206767;
    Angew. Chem. Int. Ed. 2012, 51(51), 12869–12873. DOI: 10.1002/anie.201206767
    Featured article in Advances in Engeneering News,
    Nachrichten aus der Chemie 2013, 03, 216, sowie in den
    Trendberichten 2013, 03, 236.
  50. J. Henning, H. Schubert, K. Eichele, F. Winter, R. Pöttgen, H. A. Mayer, L. Wesemann:
    Synthesis and characterization of (PNP) pincer tin(IV) and tin(II) complexes,
    Inorg. Chem. 2012, 51, 5787–5794. DOI: 10.1021/ic300324s
  51. C. Nickl, K. Eichele, L. Wesemann:
    1,2-Distanna-closo-dodecaborate – a rare example of a 1,2-distannylene ligand in transition metal chemistry,
    Dalton Trans. 2012, 41, 243–250. DOI: 10.1039/C1DT11247C
  52. --- 2011 --- [UP]

  53. S. Fleischhauer, K. Eichele, I. Schellenberg, R. Pöttgen, L. Wesemann:
    Cobalt, Rhodium, Iridium and Ruthenium Carbonyl Complexes with Stanna-closo-dodecaborate: 103Rh NMR, 119Sn Mössbauer Spectroscopy and Solid State 119Sn NMR,
    Organometallics, 2011, 30, 3200–3209. DOI: 10.1021/om200301v
  54. A. Wagenpfeil, C. Nickl, H. Schubert, K. Eichele, M. A. Fox, L. Wesemann:
    1,2-Carbagerma-closo-dodecaborate as a Germanium Ligand in Coordination Chemistry: Synthesis, Structure and Reactivity,
    Eur. J. Inorg. Chem. 2011, 3349–3356. DOI: 10.1002/ejic.201100310
  55. C. Nickl, K. Eichele, D. Joosten, T. Langer, F. M. Schappacher, R. Pöttgen, U. Englert, L. Wesemann:
    1,1,1-Tris(distanna-closo-dodecaborate)stannate: A Tripodal Tin Ligand,
    Angew. Chem. 2011, 123, 5886–5889, DOI: 10.1002/ange.201100936;
    Angew. Chem. Int. Ed. 2011, 50, 5766–5769, DOI: 10.1002/anie.201100936.
  56. J.-A. Dimmer, L. Wesemann:
    Synthesis and Structure of Tetrameric Germa-closo-dodecaborate Silver Halides,
    Z. Anorg. Allg. Chem. 2011, 637, 643–645. DOI: 10.1002/zaac.201100054
  57. J.-A. Dimmer, L. Wesemann:
    Germa-closo-dodecaborate -- An Ambident and Flexible Coordinating Ligand,
    Eur. J. Inorg. Chem. 2011, 235-240. DOI 10.1002/ejic.201000857
  58. H. Schubert, J.-A. Dimmer, F.-R. Küchle, K. Eichele, L. Wesemann:
    Homoleptic Coinage Metal Compounds of Group(IV)heteroborates,
    Inorg. Chem. 2011, 50, 664--670. DOI 10.1021/ic102118n
  59. --- 2010 --- [UP]

  60. H. Schubert, L. Wesemann:
    Silver Dimer, Tetramer, Polymer and Network Structures with the Stannylen Stanna-closo-dodecaborate,
    Organometallics 2010, 29, 4906--4913. DOI 10.1021/om1001556
  61. M. Hornung, L. Wesemann:
    Palladium Chemistry with Stanna-closo-dodecaborate and Isocyanides,
    Eur. J. Inorg. Chem. 2010, 2949-2955. DOI 10.1002/ejic.201000292
  62. J.-A. Dimmer, M. Hornung, F. Weigend, L. Wesemann:
    Chalcogen Chemistry of Group(IV)-/closo/-dodecaborates, Synthesis, Theory and Coordination Chemistry,
    Dalton. Trans. 2010, 7504-7512. DOI 10.1039/C003042B
  63. H. Schubert, F.-R. Küchle, L. Wesemann:
    Gold Cluster Chemistry with the Tin Nucleophile Stanna-closo-dodecaborate,
    Collect. Czech., Chem. Commun. 2010, 75, 963-970. DOI 10.1135/cccc2010040
  64. --- 2009 --- [UP]

  65. M. A. Fox, T. B. Marder, L. Wesemann:
    DFT Studies of the sigma-Donor/pi-Acceptor Properties of [SnCB10H11]- and its Relationship to [SnCl3]-, CO, PF3, [SnB11H11]2-, SnC2B9H11 and Related SnC2BnHn+2 Compounds,
    Can. J. Chem. 2009, 87, 63-71. DOI 10.1139/V08-081
  66. M. Kirchmann, T. Gädt, F. M. Schappacher, R. Pöttgen, F. Weigend, L. Wesemann:
    Partial Double Bond Character in Chalcogen Compounds of Stanna-closo-dodecaborate,
    Dalton Trans. 2009, 1055-1062. DOI 10.1039/b814936d
  67. N. Plumeré, B. Speiser, H. A. Mayer, D. Joosten, L. Wesemann:
    Redox-Active Silica Nanoparticles. Part 3.[+] High-Temperature Chlorination-Reduction Sequence for the Preparation of Silicon Hydride Modified Silica Surfaces.
    Chem. Eur. J. 2009, 15, 936-946. DOI 10.1002/chem.200801213
  68. C. Nickl, D. Joosten, K. Eichele, C. Maichle-Mössmer, K. W. Törnroos, L. Wesemann:
    Angew. Chem. 2009, 121, 8061-8065; DOI 10.1002/ange.200903300
    Angew. Chem. Int Ed. 2009, 48, 7920-7923.DOI 10.1002/anie.200903300
    Highlight in Nature Chemistry:
    Neil Withers, Nat. Chem. 2009, 413 DOI 10.1038/nchem.413
  69. J.-A. Dimmer, H. Schubert, L. Wesemann:
    Germa-closo-dodecaborate: A new Ligand in Transition Metal Chemistry with a Strong trans Influence
    Chem. Eur. J. 2009, 15, 10613-10619. DOI 10.1002/chem.200901308
  70. --- 2008 --- [UP]

  71. M. Kirchmann, S. Fleischhauer, L. Wesemann:
    Iridium Coordination Compounds of Stanna-closo-dodecaborate
    Organometallics 2008, 27, 2803 - 2808, DOI 10.1021/om8001679
  72. M. Kirchmann, K. Eichele, L. Wesemann:
    Homoleptic Cadmium and Mercury Compounds of Stanna-closo-dodecaborate
    Inorg. Chem. 2008, 47, 5988-5991, DOI 10.1021/ic800357z
  73. M. Kirchmann, L. Wesemann:
    Amino-closo-dodecaborate---A New Ligand in Coordination Chemistry
    Dalton Trans. 2008, 444-446, DOI 10.1039/b715305h
  74. M. Kirchmann, K. Eichele, F. M. Schappacher, R. Pöttgen, L. Wesemann:
    Octahedral Coordination Compounds of the Ni, Pd, Pt Triad
    Angew. Chem. 2008, 120, 977-980, DOI 10.1002/ange.200704814
    Angew. Chem. Int. Ed. 2008, 47, 963-966, DOI 10.1002/anie.200704814
    Siehe hierzu auch Highlight:
    S. Aldridge, Ein homoleptischer oktaedrischer Nickel(IV)-Komplex mit sehr starken Zinn(II)--Donorliganden
    Angew. Chem. 2008, 120, 2382 - 2384, DOI 10.1002/ange.200705764
    Angew. Chem. Int. Ed. 2008, 47, 2348-2350, DOI 10.1002/anie.200705764
  75. M. Kirchmann, L. Wesemann:
    h1 and h2 Coordination of 1-Amino-closo-dodecaborate
    Dalton Trans. 2008, 2144-2148, DOI 10.1039/b718569c
  76. M. Kirchmann, T. Gädt, K. Eichele, L. Wesemann:
    Nickel Coordination Compounds of Stanna-closo-dodecaborate
    Eur. J. Inorg. Chem. 2008, 2261-2265, DOI 10.1002/ejic.200800142


  1. L. Wesemann, H. Schubert, H. A. Mayer, H. Yersin, A. Rausch,
    Complex compounds comprising anionic ligands that have two P-donors, and use thereof in the optoelectronic field, WO2012EP64126 20120718.
  2. L. Wesemann, H. Schubert, H. A. Mayer, H. Yersin, A. Rausch, J. Arras,
    Complex compounds having a multidentate, asymmetric ligand and use thereof in the optoelectronic field, WO2012EP64631 20120725.
  3. L. Wesemann, H. Schubert, H. A. Mayer, S. Wernitz,
    Complex compounds having tetradentate ligands and use thereof in the optoelectronic field, WO2012EP64125 20120718.
  4. L. Wesemann, F. R. Küchle, H. A. Mayer, S. Wernitz, H. Yersin, M. Leitl,
    Electronic devices employing complex compounds comprising ligands that have an N-donor and a P-donor and their fabrication in the use of the compound to generate light, WO2013014066 (A1).
  5. P. Stoessel, D. Joosten, E. Breuning, L. Wesemann, H. Schubert,
    Electronic device, preferably organic electroluminescent device comprises a transition metal compound exhibiting a transition metal tin bond, DE201210007810 20120418.

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